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Synthesis, physicochemical characterizations and catalytic performance of Pd/carbon-zeolite and Pd/carbon-CeO

Zeinab JAMALZADEH, Mohammad HAGHIGHI, Nazli ASGARI

《环境科学与工程前沿(英文)》 2013年 第7卷 第3期   页码 365-381 doi: 10.1007/s11783-013-0520-5

摘要: In this work, xylene removal from waste gas streams was investigated via catalytic oxidation over Pd/carbon-zeolite and Pd/carbon-CeO nanocatalysts. Activated carbon was obtained from pine cone chemically activated using ZnCl and modified by H PO . Natural zeolite of clinoptilolite was modified by acid treatment with HCl, while nano-ceria was synthesized via redox method. Mixed supports of carbon-zeolite and carbon-ceria were prepared and palladium was dispersed over them via impregnation method. The prepared samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), Brunauer-Emmett-Teller surface area (BET), Fourier transform infrared spectroscopy (FTIR) and thermogravimetric (TG) techniques. Characterization of nanocatalysts revealed a good morphology with an average particle size in a nano range, and confirmed the formation of nano-ceria with an average crystallite size below 60 nm. BET analysis indicated a considerable surface area for catalysts (~1000 m ·g ). FTIR patterns demonstrated that the surface groups of synthesized catalysts are in good agreement with the patterns of materials applied in catalyst synthesis. The performance of catalysts was assessed in a low-pressure catalytic oxidation pilot in the temperature range of 100°C–250°C. According to the reaction data, the synthesized catalysts have been shown to be so advantageous in the removal of volatile organic compounds (VOCs), representing high catalytic performance of 98% for the abatement of xylene at 250°C. Furthermore, a reaction network is proposed for catalytic oxidation of xylene over nanocatalysts.

关键词: Pd/carbon-CeO2     Pd/carbon-zeolite     pine cone     ZnCl2     catalytic oxidation     xylene    

Adsorption of herring sperm DNA onto pine sawdust biochar: Thermodynamics and site energy distribution

《环境科学与工程前沿(英文)》 2022年 第16卷 第11期 doi: 10.1007/s11783-022-1579-7

摘要:

● Adsorption of environmental deoxyribonucleic acid on biochar was studied.

关键词: Environmental deoxyribonucleic acid     Antibiotic resistance genes     Biochar     Adsorption thermodynamics    

Liquefaction prediction using support vector machine model based on cone penetration data

Pijush SAMUI

《结构与土木工程前沿(英文)》 2013年 第7卷 第1期   页码 72-82 doi: 10.1007/s11709-013-0185-y

摘要: A support vector machine (SVM) model has been developed for the prediction of liquefaction susceptibility as a classification problem, which is an imperative task in earthquake engineering. This paper examines the potential of SVM model in prediction of liquefaction using actual field cone penetration test (CPT) data from the 1999 Chi-Chi, Taiwan earthquake. The SVM, a novel learning machine based on statistical theory, uses structural risk minimization (SRM) induction principle to minimize the error. Using cone resistance ( ) and cyclic stress ratio ( ), model has been developed for prediction of liquefaction using SVM. Further an attempt has been made to simplify the model, requiring only two parameters ( and maximum horizontal acceleration ), for prediction of liquefaction. Further, developed SVM model has been applied to different case histories available globally and the results obtained confirm the capability of SVM model. For Chi-Chi earthquake, the model predicts with accuracy of 100%, and in the case of global data, SVM model predicts with accuracy of 89%. The effect of capacity factor ( ) on number of support vector and model accuracy has also been investigated. The study shows that SVM can be used as a practical tool for prediction of liquefaction potential, based on field CPT data.

关键词: earthquake     cone penetration test     liquefaction     support vector machine (SVM)     prediction    

Impingement of hollow cone spray on hot porous medium

ZHAO Zhiguo, XIE Maozhao

《能源前沿(英文)》 2008年 第2卷 第3期   页码 273-278 doi: 10.1007/s11708-008-0048-8

摘要: To have a good understanding of the formation of homogenous mixture in a porous medium engine, the interaction between hollow cone spray and hot porous medium was studied numerically by using an improved version of KIVA-3V code. The improved KIVA-3V code is incorporated with an impingement model, heat transfer model and linearized instability sheet atomization (LISA) model to simulate the hollow cone spray. The reasonability of the impingement model and heat transfer model was validated. With a simple model to describe the structure of the porous medium, the interaction between hollow cone spray and hot porous medium was simulated under different ambient pressures and spray cone angles. Computational results show that the fuel spray could be divided into smaller ones, which provides conditions for the quick evaporation of fuel droplets and the mixing of fuel vapor with air. Differences in ambient pressure and spray cone angle affect the distribution of droplets in the porous medium.

关键词: improved version     simple     impingement     atomization     hollow    

of undercut on the lower bound stability of vertical rock escarpment using finite element and power cone

《结构与土木工程前沿(英文)》 doi: 10.1007/s11709-023-0035-5

摘要: Correction to: Effect of undercut on the lower bound stability of vertical rock escarpment using finite element and power cone programming

关键词: finite element power     stability rock escarpment    

of undercut on the lower bound stability of vertical rock escarpment using finite element and power cone

Shuvankar DAS; Debarghya CHAKRABORTY

《结构与土木工程前沿(英文)》 2022年 第16卷 第8期   页码 1040-1055 doi: 10.1007/s11709-022-0841-1

摘要: In the present study, the stability of a vertical rock escarpment is determined by considering the influence of undercut. Lower bound finite element limit analysis in association with Power Cone Programming (PCP) is applied to incorporate the failure of rock mass with the help of the Generalized Hoek-Brown yield criterion. The change in stability due to the presence of undercut is expressed in terms of a non-dimensional stability number (σci/γH). The variations of the magnitude of σci/γH are presented as design charts by considering the different magnitudes of undercut offset (H/vu and wu/vu) from the vertical edge and different magnitudes of Hoek-Brown rock mass strength parameters (Geological Strength Index (GSI), rock parameter (mi,), Disturbance factor (D)). The obtained results indicate that undercut can cause a severe stability problem in rock mass having poor strength. With the help of regression analysis of the computed results, a simplified design equation is proposed for obtaining σci/γH. By performing sensitivity analysis for an undisturbed vertical rock escarpment, we have found that the undercut height ratio (H/vu) is the most sensitive parameter followed by GSI, undercut shape ratio (wu/vu), and mi. The developed design equation as well as design charts can be useful for practicing engineers to determine the stability of the vertical rock escarpment in the presence of undercut. Failure patterns are also presented to understand type of failure and extent of plastic state during collapse.

关键词: undercut     vertical escarpment     stability     Hoek-Brown yield criterion     PCP    

Impacts of cone-structured interface and aperiodicity on nanoscale thermal transport in Si/Ge superlattices

Pengfei JI, Yiming RONG, Yuwen ZHANG, Yong TANG

《能源前沿(英文)》 2018年 第12卷 第1期   页码 137-142 doi: 10.1007/s11708-018-0532-8

摘要: Si/Ge superlattices are promising thermoelectric materials to convert thermal energy into electric power. The nanoscale thermal transport in Si/Ge superlattices is investigated via molecular dynamics (MD) simulation in this short communication. The impact of Si and Ge interface on the cross-plane thermal conductivity reduction in the Si/Ge superlattices is studied by designing cone-structured interface and aperiodicity between the Si and Ge layers. The temperature difference between the left and right sides of the Si/Ge superlattices is set up for nonequilibrium MD simulation. The spatial distribution of temperature is recorded to examine whether the steady-state has been reached. As a crucial factor to quantify thermal transport, the temporal evolution of heat flux flowing through Si/Ge superlattices is calculated. Compared with the even interface, the cone-structured interface contributes remarkable resistance to the thermal transport, whereas the aperiodic arrangement of Si and Ge layers with unequal thicknesses has a marginal influence on the reduction of effective thermal conductivity. The interface with divergent cone-structure shows the most excellent performance of all the simulated cases, which brings a 33% reduction of the average thermal conductivity to the other Si/Ge superlattices with even, convergent cone-structured interfaces and aperiodic arrangements. The design of divergent cone-structured interface sheds promising light on enhancing the thermoelectric efficiency of Si/Ge based materials.

关键词: thermoelectric material     thermal transport     Si/Gesuperlattics     molecular dynamics (MD)    

Study of high-strength CFRP bolted joints with failure- monitoring cone washers

Tsukasa KATSUMATA, Yoshihiro MIZUTANI, Akira TODOROKI, Ryosuke MATSUZAKI

《机械工程前沿(英文)》 2011年 第6卷 第3期   页码 272-276 doi: 10.1007/s11465-011-0231-1

摘要:

To increase the strength of carbon-fiber-reinforced plastic (CFRP) bolted joints, a method to increase the friction force between carbon-fiber-reinforced plastic members was proposed. The increase in failure load for the proposed joint was confirmed in finite-element method analyses and joint tests. Additionally, the feasibility of damage monitoring using surface strains of the cone washer was demonstrated.

关键词: composite     bolted joint     failure monitoring     finite-element method    

基于人工智能技术的无人机遥感探测具有感染松材线虫病特征的树木 Article

Mutiara Syifa, Sung-Jae Park, Chang-Wook Lee

《工程(英文)》 2020年 第6卷 第8期   页码 919-926 doi: 10.1016/j.eng.2020.07.001

摘要:

最近,松材线虫病(PWD)导致韩国大量的松树受损。鉴于松树对于韩国人的重要性,PWD被视为一个严重的问题,因此必须妥善处理这个问题。先前我们调查了PWD的历史,发现它已扩散到韩国的一些地区,这些成为了我们的研究领域。必须尽早对PWD进行检测。我们利用无人机遥感技术来探测具有与感染松材线虫病的树木相似症状的树木。之所以使用无人机遥感,是因为它能够生成高质量的图像,并且可以很容易地到达松树的位置。为了区别健康的和感染了PWD的松树,我们利用从Anbi和Wonchang两村采集到的无人机图像制作了一份土地覆盖图(LC),使用两种方法将它们分类,即人工神经网络(ANN)和支持向量机(SVM)。此外,比较了使用无人机和手持设备收集的两类全球定位系统(GPS)数据的准确性,以确定感染PWD的树木的位置。随后,我们将每个研究区域的无人机图像分成6个LC类,发现SVM在区分是否感染PWD的树木时比ANN更准确。在Anbi村,SVM的总体准确率为94.13%,与ANN总体准确率87.43%相比,高出了6.7%。在Wonchang村我们也得到了相似的结果,SVM和ANN的准确率分别为86.59%和79.33%。在GPS数据方面,我们使用了两种手持GPS设备。GPS设备1参照两个位置的基准点来校正,GPS设备2为未校正设备,仅使用GPS的默认设置。在Wonchang,手持GPS设备1采集的数据优于手持GPS设备2。然而,在Anbi,GPS设备2获得的结果优于GPS设备1获得的结果:GPS设备1的数据误差为7.08 m,而GPS设备2的数据误差为0.14 m。总的来说,这两种分类器都能根据LC数据辨别健康树木和患有PWD的树木。LC数据也可以用于其他类型的分类。这两个区域的手持GPS数据集和无人机GPS数据集存在一些差异。
 

关键词: 松材线虫病     无人机遥感     人工神经网络     支持向量机     全球定位系统    

Prediction of the shear wave velocity

Amoroso SARA

《结构与土木工程前沿(英文)》 2014年 第8卷 第1期   页码 83-92 doi: 10.1007/s11709-013-0234-6

摘要: The paper examines the correlations to obtain rough estimates of the shear wave velocity from non-seismic dilatometer tests (DMT) and cone penetration tests (CPT). While the direct measurement of is obviously preferable, these correlations may turn out useful in various circumstances. The experimental results at six international research sites suggest that the DMT predictions of from the parameters (material index), (horizontal stress index), (constrained modulus) are more reliable and consistent than the CPT predictions from (cone resistance), presumably because of the availability, by DMT, of the stress history index .

关键词: horizontal stress index     shear wave velocity     flat dilatometer test     cone penetration test    

Modular structure of a self-reconfigurable robot

FEI Yanqiong, DONG Qinglei, ZHAO Xifang

《机械工程前沿(英文)》 2007年 第2卷 第1期   页码 116-119 doi: 10.1007/s11465-007-0020-z

摘要: This paper proposes a novel, hermaphroditic, and lattice self-reconfigurable modular robot. Each module is composed of a center body a cubic part and six sides that can rotate independently. There are two holes and two extensible pegs on each side. The rotary motion of each side and the extensible motion of the pegs are generated by a motor connected to a reducer, using a cone-shaped gear, belt, clutch, etc. The structure of the module is compact, and has space to extend further.

关键词: compact     self-reconfigurable modular     hermaphroditic     cone-shaped     clutch    

In situ-based assessment of soil liquefaction potential–Case study of an earth dam in Tunisia

Ikram GUETTAYA,Mohamed Ridha EL OUNI

《结构与土木工程前沿(英文)》 2014年 第8卷 第4期   页码 456-461 doi: 10.1007/s11709-014-0259-5

摘要: The present paper examines the evaluation of liquefaction potential of an earth dam foundation in Tunisia. The assessment of soil liquefaction was made using deterministic and probabilistic simplified procedures developed from several case histories. The data collected from the field investigation performed before and after the vibrocompaction are analyzed and the results are reported. The obtained results show that after vibrocompaction, a significant improvement of the soil resistance reduces the liquefaction potential of the sandy foundation. Indeed, in the untreated layers, the factor of safety drops below 1 which means that the soil is susceptible for liquefaction. However, in the compacted horizons, the values of exceed the unit which justifies the absence of liquefaction hazard of the foundation.

关键词: liquefaction     cone penetration test (CPT)     standard penetration test (SPT)     vibrcompaction     sand    

Influence of surface cracking, anchor head profile, and anchor head size on cast-in headed anchors in geopolymer concrete

《结构与土木工程前沿(英文)》   页码 1163-1187 doi: 10.1007/s11709-023-0987-5

摘要: In this study, the concrete cone capacity, concrete cone angle, and load–displacement response of cast-in headed anchors in geopolymer concrete are explored using numerical analyses. The concrete damaged plasticity (CDP) model in ABAQUS is used to simulate the behavior of concrete substrates. The tensile behavior of anchors in geopolymer concrete is compared with that in normal concrete as well as that predicted by the linear fracture mechanics (LFM) and concrete capacity design (CCD) models. The results show that the capacity of the anchors in geopolymer concrete is 30%–40% lower than that in normal concrete. The results also indicate that the CCD model overestimates the capacity of the anchors in geopolymer concrete, whereas the LFM model provides a much more conservative prediction. The extent of the difference between the predictions by the numerical analysis and those of the above prediction models depends on the effective embedment depth of the anchor and the anchor head size. The influence of concrete surface cracking on the capacity of the anchor is shown to depend on the location of the crack and the effective embedment depth. The influence of the anchor head profile on the tensile capacity of the anchors is found to be insignificant.

关键词: cast-in anchor     concrete cone capacity     geopolymer concrete     head size     surface crack     anchor profile    

Application of machine learning algorithms for the evaluation of seismic soil liquefaction potential

Mahmood AHMAD, Xiao-Wei TANG, Jiang-Nan QIU, Feezan AHMAD, Wen-Jing GU

《结构与土木工程前沿(英文)》 2021年 第15卷 第2期   页码 490-505 doi: 10.1007/s11709-020-0669-5

摘要: This study investigates the performance of four machine learning (ML) algorithms to evaluate the earthquake-induced liquefaction potential of soil based on the cone penetration test field case history records using the Bayesian belief network (BBN) learning software Netica. The BBN structures that were developed by ML algorithms-K2, hill climbing (HC), tree augmented naive (TAN) Bayes, and Tabu search were adopted to perform parameter learning in Netica, thereby fixing the BBN models. The performance measure indexes, namely, overall accuracy ( ), precision, recall, , and area under the receiver operating characteristic curve, were used to evaluate the training and testing BBN models’ performance and highlight the capability of the K2 and TAN Bayes models over the Tabu search and HC models. The sensitivity analysis results showed that the cone tip resistance and vertical effective stress are the most sensitive factors, whereas the mean grain size is the least sensitive factor in the prediction of seismic soil liquefaction potential. The results of this study can provide theoretical support for researchers in selecting appropriate ML algorithms and improving the predictive performance of seismic soil liquefaction potential models.

关键词: seismic soil liquefaction     Bayesian belief network     cone penetration test     parameter learning     structural learning    

用锥形量热仪研究细水雾抑制熄灭PVC火

黄鑫,刘江虹,张永丰,秦俊

《中国工程科学》 2006年 第8卷 第12期   页码 102-106

摘要:

利用锥形量热仪和单流体细水雾系统研究了细水雾抑制PVC火的过程,并观察了重燃现象的发生,测量了实验中热释放速率及O2,CO2,CO和烟气的浓度变化,并对不同细水雾工作压力及不同热辐射流量下的结果进行了比较。由实验可知细水雾能快速扑灭PVC火,且压力越大灭火越迅速,但是在灭火后停止施加细水雾会发生重燃现象,且重燃发生的时间长短与作用在燃料表面的水量有关。

关键词: PVC火     细水雾     热释放速率     重燃    

标题 作者 时间 类型 操作

Synthesis, physicochemical characterizations and catalytic performance of Pd/carbon-zeolite and Pd/carbon-CeO

Zeinab JAMALZADEH, Mohammad HAGHIGHI, Nazli ASGARI

期刊论文

Adsorption of herring sperm DNA onto pine sawdust biochar: Thermodynamics and site energy distribution

期刊论文

Liquefaction prediction using support vector machine model based on cone penetration data

Pijush SAMUI

期刊论文

Impingement of hollow cone spray on hot porous medium

ZHAO Zhiguo, XIE Maozhao

期刊论文

of undercut on the lower bound stability of vertical rock escarpment using finite element and power cone

期刊论文

of undercut on the lower bound stability of vertical rock escarpment using finite element and power cone

Shuvankar DAS; Debarghya CHAKRABORTY

期刊论文

Impacts of cone-structured interface and aperiodicity on nanoscale thermal transport in Si/Ge superlattices

Pengfei JI, Yiming RONG, Yuwen ZHANG, Yong TANG

期刊论文

Study of high-strength CFRP bolted joints with failure- monitoring cone washers

Tsukasa KATSUMATA, Yoshihiro MIZUTANI, Akira TODOROKI, Ryosuke MATSUZAKI

期刊论文

基于人工智能技术的无人机遥感探测具有感染松材线虫病特征的树木

Mutiara Syifa, Sung-Jae Park, Chang-Wook Lee

期刊论文

Prediction of the shear wave velocity

Amoroso SARA

期刊论文

Modular structure of a self-reconfigurable robot

FEI Yanqiong, DONG Qinglei, ZHAO Xifang

期刊论文

In situ-based assessment of soil liquefaction potential–Case study of an earth dam in Tunisia

Ikram GUETTAYA,Mohamed Ridha EL OUNI

期刊论文

Influence of surface cracking, anchor head profile, and anchor head size on cast-in headed anchors in geopolymer concrete

期刊论文

Application of machine learning algorithms for the evaluation of seismic soil liquefaction potential

Mahmood AHMAD, Xiao-Wei TANG, Jiang-Nan QIU, Feezan AHMAD, Wen-Jing GU

期刊论文

用锥形量热仪研究细水雾抑制熄灭PVC火

黄鑫,刘江虹,张永丰,秦俊

期刊论文